The Bluetooth button on the back will not help the Era 300 connect to Wi-Fi. A blue LED means that it is connected over Bluetooth or in pairing mode when it is flashing blue, but Bluetooth is disabled when being used as a surround.
If you are not having any trouble with your other Sonos devices, I’d factory reset the missing Era 300 and add it back to your system.
You would need to select remove surrounds, then add the surrounds again when both are visible in the app.
https://support.sonos.com/en-gb/article/sonos-led-lights
https://support.sonos.com/en-gb/article/reset-your-sonos-product