Hi @Alleddie
Welcome to the Sonos Community!
I can see your Era 300s are in a stereo pair as @AjTrek1 maybe suspected, which means that unlike with other input sources which will group successfully thanks to buffering, TV audio does not group with other speakers well as your Arc is unwilling to wait for buffering, as that would result in a lip-sync issue with the TV. It does work, but performance is entirely down to local conditions which may or may not be possible to improve. So, although not everyone has issues in this situation, it is somewhat expected.
As @Airgetlam rightly pointed out, a Boost would not help in this situation, as the Eras will not utilise SonosNet. On WiFi, Arc will be connecting to the slower 2.4GHz band on your router, so assuming there is no interference anywhere, the only thing you can do to possibly improve performance is to connect the Arc to the router with an ethernet cable.
Please note, however, that interference could easily be a factor. If music sources play in sync across both rooms without issue, then you can worry less about it. Interference at the Arc, the router or the Eras would cause issues, and our Reducing wireless interference help page can help you identify sources.
I hope this helps.
"Common sense is the collection of prejudices acquired by age eighteen." - Albert Einstein